Schrödinger equation

Level SpecializationDifficulty ★★★★★Application⌖ Open in the map

What is it?

The PDE for the time evolution of a wave function: iℏ ∂tψ=H^ψi\hbar\,\partial_t\psi = \hat H\psi, with the Hamiltonian built from the Laplacian (kinetic energy) and a potential. Its operators — derivatives acting on functions — are where calculus and linear algebra meet; in quantum computing the same equation becomes ∣ψ(t)⟩=e−iHt/ℏ∣ψ(0)⟩|\psi(t)\rangle = e^{-iHt/\hbar}|\psi(0)\rangle.

Formulas

iℏ ∂ψ∂t=−ℏ22m Δψ+V(x) ψi\hbar\,\frac{\partial\psi}{\partial t} = -\frac{\hbar^2}{2m}\,\Delta\psi + V(x)\,\psi
p^=−iℏ ∂∂x\hat p = -i\hbar\,\frac{\partial}{\partial x}
momentum is a derivative operator

The mathematics behind it

  • Laplacian★★★★★fundamental

    Kinetic energy in quantum mechanics is −ℏ22mΔ-\frac{\hbar^2}{2m}\Delta.

This page has the essentials. A fuller treatment (intuition, formal definition, worked example) is on the way.

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